1. A High-performance Chiral ¹⁹F-Labeled Probe with an Increased Structural Twisting

Chenyang Wang,  Guangxing Gu, Wei Zhang, Jian Wu, and Yanchuan Zhao*

Chem. Commun. 2024, doi: 10.1039/D4CC01313A 文章链接 

 

 

2. Detection and Identification of Nitrile Compounds via Recognition-Enabled Chromatographic ¹⁹F NMR

Wenjing Bao,  Guangxing Gu, Jian Wu, Yu-Cheng Gu, and Yanchuan Zhao*

Anal. Chem.  2024, 96, 6463–6468. 文章链接 

 

 

 

3. Conformational Locking as a Strategy to Reverse Ion Recognition Selectivity

Wei Zhang,  Chong Zhao, Wenjie Zhu, Xiao He*, and Yanchuan Zhao*

J. Org. Chem.  2024, 89, 4037–4041. 文章链接 

 

 

 

4. Enantiodifferentiation of Chiral Diols and Diphenols via Recognition-Enabled Chromatographic ¹⁹F NMR

Yilin Zeng,  Wenjing Bao, Guangxing Gu, and Yanchuan Zhao*

Magn. Reson. Lett.  2024, doi: 10.1016/j.mrl.2024.200112. 文章链接 分析人亮点介绍

 

 

5. Bioinspired Organic Porous Coupling Agent for Enhancement of Nanoparticle Dispersion and Interfacial Strength

Qi Jia,  and Yanchuan Zhao*

ACS Appl. Mater. Interfaces 2024, 16, 6403–6413. 文章链接 科研留声机亮点介绍

 

 

 

6. Chiral Discrimination of Acyclic Secondary Amines by ¹⁹F NMR

Guangxing Gu, Chong Zhao, Wei Zhang, Jiajin Weng, Zhenchuang Xu, Jian Wu, Yingbo Xie, Xiao He*, and Yanchuan Zhao*

Anal. Chem. 2024, 96, 730–736. 文章链接  分析人亮点介绍

 

1. Layered Porous Molecular Crystals via Interdigitation-Directed Assembly

Nie Fang , Siquan Zhang, Zhenchuang Xu, Si Chen, Xu Zhang, Hui Wu, Wei Zhou, and Yanchuan Zhao*

Cell. Rep. Phys. Sci. 2023, 101508. 文章链接  Phy.Org  上海有机所微信公众号

 

 

 

2. Improving the Sensitivity of Enantioanalysis with Densely Fluorinated NMR Probes

Yushu Jia , Lixian Wen, Wenjing Bao, Zhenchuang Xu, Jian Wu, and Yanchuan Zhao*

Anal. Chem. 2023, 95, 10362–10367. 文章链接  分析人亮点介绍

 

 

 

3. Chiral Discrimination of Nitrile Compounds Using a ¹⁹F-Labeled Palladium Probe

Guangxing Gu , Yue Yue, Chengyang Wang, Wei Zhang, Jian Wu, Ya Li*,  and Yanchuan Zhao*

Org. Lett.  2023, 25, 4819–4824. 文章链接  CBG亮点介绍

 

 

 

4. Research Progress on Organic Cation Receptors Based on Molecular Containers

Wenjie Zhu , Zhenchuang Xu, Yu-Cheng Gu, and Yanchuan Zhao*

Chin. J. Org. Chem. 2023, doi: 10.6023/cjoc202303028. 文章链接  有机化学亮点介绍

 

 

 

5. Chirality Sensing of N-Heterocycles via ¹⁹F NMR

Guangxing Gu, Zhenchuang Xu, Lixian Wen, Jinhua Liang, Chenyang Wang, Xiaolong Wan, and Yanchuan Zhao*

JACS Au 2023, 3, 1348–1357. 文章链接   ACS Publications亮点介绍  上海有机所微信公众号

 

 

 

6. Tailoring the Recognition Property of a ¹⁹F-Labeled Gallium-Based NMR Probe: The Influence of the Metal Center

Jinhua Liang, Zhenchuang Xu, Jian Wu, and Yanchuan Zhao*

Anal. Chem. 2023, 95, 7569–7574. 文章链接 分析人亮点介绍

 

 

7. ¹⁹F-Labeled Probes for Recognition-Enabled Chromatographic ¹⁹F NMR

Zhenchuang Xu, and Yanchuan Zhao*

Chem. Rec. 2023, e202300031. 文章链接

 

 

 

8. Detection and Identification of Amphetamine-Type Stimulants and Analogs via Recognition-Enabled “Chromatographic” ¹⁹F NMR.

Jiayu Jiang, Lixian Wen, Hongshuang Wang, Xiaoguang Chen,* Yanchuan Zhao,* and Xiaohui Wang*

J. Fluorine Chem. 2023, 15, 110085. 文章链接 分析人亮点介绍

 

 

 

9. ¹⁹F-labeled molecular probes for NMR-based detection

Zhenchuang Xu, and Yanchuan Zhao*

J. Fluorine Chem. 2023, 15, 110089. 文章链接

 

1. Tailoring Sensors and Solvents for Optimal Analysis of Complex Mixtures Via Discriminative ¹⁹F NMR Chemosensing. 

Chanjuan Dong, Zhenchuang Xu, Lixian Wen, Shengyuan He, Jian Wu, Qing-Hai Deng*, and Yanchuan Zhao*

Anal. Chem. 2021, 93, 2968–2973.  文章链接  X-mol亮点介绍 分析人亮点介绍

 

 

 

2. Calix[4]trap: A Bioinspired Host Equipped with Dual Selection Mechanisms.

Zhenchuang Xu, Nie Fang, and Yanchuan Zhao*

J. Am. Chem. Soc. 2021, 143, 3162–3168. 文章链接  有机所官网介绍  中科院官网转载  CBG #人物与科研#

 

 

 

3. Synthesis and Characterization of Diastereoisomeric Polyesters Derived from Bisphenols Bearing Vicinal Trifluoromethyl Groups.

Jinghuang Lv, Si Chen, Zhenchuang Xu, Siquan Zhang, Ya Li*, and Yanchuan Zhao*

Macromolecules 2021, 54, 3716–3724. 文章链接

 

 

 

4. Difluorocarbene-Mediated Cascade Cyclization: The Multifunctional Role of Ruppert–Prakash Reagent

Yanyao Cai, Wenjie Zhu, Shujuan Zhao, Chanjuan Dong, Zhenchuang Xu, and Yanchuan Zhao*

Org. Lett. 2021, 23,  3546–3551. 文章链接

 

 

5. Achieving Efficient Organic Solar Cells via Synergistically Doping Active Layers and Interfaces by a Conjugated Macrocycle.

Yan Wang, Yi Zhang, Tong Shan, Qingyun Wei, Zhenchuang Xu, Yanchuan Zhao, Jianming Yang, Qinye Bao, Hui Jin, Zaifei Ma, Hao Wei and Hongliang Zhong*

J. Mater. Chem. A, 2021, 9, 25629–25640. 文章链接

 

                                                  

1. Separation-free Enantiodifferentiation with Chromatogram-like Output. 

Yipeng Li, Lixian Wen, Huan Meng, Jinghuang Lv, Gen Luo, and Yanchuan Zhao* 

Cell Reports Physical Science , 2020, 1, 100100.  文章链接 中科院官网介绍 有机所官网介绍

 

 

 

2. Poly(o‐xylylene)s via Cobalt‐Catalyzed Reductive Polymerization. 

Si Chen and Yanchuan Zhao* 

Chin. J. Chem. 2020, 38, 952–958. 文章链接

 

 

 

3. C_sp³-C_sp³ Bond Formation Via Transition-metal Mediated and Catalyzed Reductive Homocouplings.

Si Chen and Yanchuan Zhao* 

Chin. J. Org. Chem. 2020, 40, 3078–3093.  文章链接

 

 

1. Molecular Sensors for NMR-Based Detection. 

Zhenchuang Xu, Chao Liu, Shujuan Zhao, Si Chen, and Yanchuan Zhao* 

Chem. Rev. 2019, 119 , 195–230. 文章链接

  

 

2. Waveguide-based chemo- and biosensors: complex emulsions for the detection of caffeine and proteins. 

Lukas Zeininger, Elisabeth Weyandt, Suchol Savagatrup, Kent S. Harvey, Qifan Zhang, Yanchuan Zhao, and Timothy M. Swager* 

Lab. Chip. 2019, 19, 1327–1331. 文章链接

  

 

3. Polymers with Side Chain Porosity for Ultrapermeable and Plasticization Resistant Materials for Gas Separations. 

Yuan He, Francesco M. Benedetti, Sharon Lin, Chao Liu, Yanchuan Zhao, Hong‐Zhou Ye, Troy Van Voorhis, M. Grazia De Angelis, Timothy M. Swager, Zachary P. Smith*

Adv. Mater. 2019, 31 , 1807871. 文章链接  MIT NEWS亮点介绍

  

 

4. Nonafluoro-tert-butoxylation of Diaryliodonium Salts. 

Huan Meng, Lixian Wen, Zhenchuang Xu, Yipeng Li, Jian Hao* and Yanchuan Zhao* 

Org. Lett. 2019, 21, 5216–5210. 文章链接

  

 

1. Recent advances in mechanochemical C–H functionalization reactions. 

Shujuan Zhao, Yipeng Li, Chao Liu, Yanchuan Zhao* 

Tetrahendron Lett. 2018, 59, 317–324.  文章链接           

 

 

2. Porous Organic Polymers via Ring Opening Metathesis Polymerization. 

Yanchuan Zhao, Yuan He, and Timothy M. Swager* 

ACS Marco Lett. 2018, 7 , 300–304. 文章链接     

 

 

3. Conformation of bis-nitroxide polarizing agents by multi-frequency EPR spectroscopy. 

Janne Soetbeer, Peter Gast, Joseph J. Walish, Yanchuan Zhao, Christy George, Chen Yang, Timothy M. Swager, Robert G. Griffin, and Guinevere Mathies*

Phys. Chem. Chem. Phys. 2018, 20, 25506–25517. 文章链接  

 

 

4. Iron-Catalyzed Difluoromethylation of Arylzincs with Difluoromethyl 2-Pyridyl Sulfone. 

Wenjun Miao, Yanchuan Zhao, Chuanfa Ni, Bing Gao, Wei Zhang, and Jinbo Hu* 

J. Am. Chem. Soc. 2018, 140 , 880–883.  文章链接 

 

 

5. Synthesis of 2,2-diaryl-1,1-difluoroethenes via Pd-catalyzed dehydrosulfonylative cross-coupling of α-[difluoro(phenylsulfonyl)methyl]benzyl tosylates with arylboronic acids. 

Rui Zhang, Chuanfa Ni, Yanchuan Zhao, and Jinbo Hu*

Tetrahedron 2018, 74 , 5295–5302. 文章链接 

 

 

1. Mechanochemical Synthesis of Extended Iptycenes. 

Yanchuan Zhao, Silvia V. Rocha, and Timothy M. Swager* 

J. Am. Chem. Soc. 2016, 138 , 13834–13837.  文章链接 

 

 

2. Simultaneous Identification of Neutral and Anionic Species in Complex Mixtures without Separation. 

Yanchuan Zhao, Lily Chen, and Timothy M. Swager* 

Angew. Chem. Int. Ed. 2016, 55 , 917–921.  文章链接

 

 

 

3. Bis(difluoromethyl)trimethylsilicate Anion: A Key Intermediate in Nucleophilic Difluoromethylation of Enolizable Ketones with Me₃SiCF₂H. 

Dingben Chen, Chuanfa Ni, Yanchuan Zhao, Xian Cai, Xinjin Li, Pan Xiao, and  Jinbo Hu* 

Angew. Chem. Int. Ed. 2016, 55, 12632–12636.   文章链接       

 

 

 

4. Nucleophilic Iododifluoromethylation of Carbonyl Compounds Using Difluoromethyl 2-Pyridyl Sulfone. 

Wenjun Miao, Chuanfa Ni, Yanchuan Zhao, and Jinbo Hu* 

Org. Lett. 2016, 18, 2766-2769. 文章链接        

 

 

 

1. Functionalized Metalated Cavitands via Imidation and Late‐Stage Elaboration. 

Yanchuan Zhao, and Timothy M. Swager* 

Eur. J. Org. Chem. 2015, 121,  4593-4597.  文章链接

 

 

2. Spontaneous Resolution of Julia-Kocienski Intermediates Facilitates Phase Separation to Produce Z- and E-Monofluoroalkenes.

Yanchuan Zhao, Fanzhou Jiang, and Jinbo Hu* 

J. Am. Chem. Soc. 2015, 137, 5199-5203. 文章链接

 

 

3. Simultaneous Chirality Sensing of Multiple Amines by ¹⁹F NMR. 

Yanchuan Zhao and Timothy M. Swager* 

J. Am. Chem. Soc. 2015, 137 , 3221-3224.  文章链接  ChemistryViews亮点评述  C&E NEWs亮点评述  Chem-Station亮点评述 

 

 

4. Carbonyl olefination of diaryl ketones with heteroaryl sulfoxides.

Bing Gao, Jingyu Hu, Yanchuan Zhao, Jinbo Hu* 

Tetrahedron Lett. 2015, 56, 4180-4183.  文章链接

 

 

5. Difluoromethyl 2-pyridyl sulfone: a versatile carbonyl gem-difluoroolefination reagent.

Bing Gao, Yanchuan Zhao, Jingyu Hua and Jinbo Hu* 

J. Org. Chem. Front. 2015, 2,  163-168.  文章链接

 

 

6. AgF‐Mediated Fluorinative Cross‐Coupling of Two Olefins: Facile Access to α‐CF₃ Alkenes and β‐CF₃ Ketones.

Bing Gao, Yanchuan Zhao, and Jinbo Hu* 

Angew. Chem. Int. Ed. 2015, 54 , 638-642. 文章链接

 

 

​

1. ¹⁹F NMR Fingerprints: Identification of Neutral Organic Compounds in a Molecular Container. 

Yanchuan Zhao, Georgios Markopoulos, and Timothy M. Swager* 

J. Am. Chem. Soc. 2014, 136 , 10683-10690. 文章链接

 

 

2.  Radical (2-pyridylsulfonyl)difluoromethylation of terminal alkenes with iododifluoromethyl 2-pyridyl sulfone. 

Wemjun Miao, Chuanfa Ni, Yanchuan Zhao and Jinbo Hu*  
J. Fluorine Chem. 2014, 167, 231-236. 文章链接

 

 

3. gem‐Difluoroolefination of Diaryl Ketones and Enolizable Aldehydes with Difluoromethyl 2‐Pyridyl Sulfone: New Insights into the Julia–Kocienski Reaction. 

Bing Gao, Yanchuan Zhao, Mingyou Hu, Chuanfa Ni, and Jinbo Hu* 

Chem. Eur. J. 2014, 20, 7803-7810. 文章链接

 

 

4. Selective monofluorination of active methylene compounds: the important role of ZnCl₂ in inhibiting overfluorination.

Fanzhou Jiang, Yanchuan Zhao, and Jinbo Hu* 

Org. Chem. Front. 2014, 625-629. 文章链接

 

 

1. Copper-Catalyzed Debenzoylative Monofluoromethylation of Aryl Iodides Assisted by the Removable (2-Pyridyl)sulfonyl Group. 

Yanchuan Zhao, Chuanfa Ni, Fanzhou Jiang, Bing Gao, Xiao Shen, and Jinbo Hu* 

ACS Catal. 2013, 3 , 631-634. 文章链接

 

 

 

2. Detection and Differentiation of Neutral Organic Compounds by ¹⁹F NMR with a Tungsten Calix[4]arene Imido Complex. 

Yanchuan Zhao, and Timothy M. Swager* 

J. Am. Chem. Soc. 2013, 135 , 18770-18773. 文章链接

 

 

 

3. Silver-Mediated Trifluoromethylation–Iodination of Arynes. 

Yuwen Zeng, Laijun Zhang, Yanchuan Zhao, Chuanfa Ni, Jingwei Zhao, and Jinbo Hu* 

J. Am. Chem. Soc. 2013, 135 , 2955-2958. 文章链接

 

 

 

4. DIAD-mediated metal-free cross dehydrogenative coupling between tertiary amines and α-fluorinated sulfones.  

Weizhou Huang, Chuanfa Ni, Yanchuan Zhao and Jinbo Hu* 

New J. Chem. 2013, 37 , 1684-1687. 文章链接

 

 

1. Copper-Mediated Fluoroalkylation of Aryl Iodides Enables Facile Access to Diverse Fluorinated Compounds: The Important Role of the (2-Pyridyl)sulfonyl Group. 

Yanchuan Zhao, Bing Gao, Chuanfa Ni, and Jinbo Hu* 

Org. Lett. 2012, 14 , 6080-6083. 文章链接

 

 

2. From Olefination to Alkylation: In-Situ Halogenation of Julia–Kocienski Intermediates Leading to Formal Nucleophilic Iodo- and Bromodifluoromethylation of Carbonyl Compounds. 

Yanchuan Zhao, Bing Gao, and Jinbo Hu* 

J. Am. Chem. Soc. 2012, 134 , 5790-5793. 文章链接

 

 

3. Palladium‐Catalyzed 2,2,2‐Trifluoroethylation of Organoboronic Acids and Esters. 

Yanchuan Zhao, and Jinbo Hu* 

Angew. Chem. Int. Ed. 2012, 51, 1033-1036. 文章链接

 

 

4. Palladium-catalyzed allylation of 2,2,2-trifluoroethyl phenyl sulfone, a potential 2,2,2-trifluoroethyl pronucleophile. 

Wei Zhang, Yanchuan Zhao, Chuanfa Ni, Thomas Mathew, and Jinbo Hu* 

Tetrahedron Lett. 2012, 53 , 6565-6568. 文章链接

 

 

5. Nucleophilic difluoromethylation of N,N-acetals with TMSCF₂SO₂Ph reagent promoted by trifluoroacetic acid: A facile access to α-difluoromethylated tertiary amines. 

Weizhou Huang, Chuanfa Ni, Yanchuan Zhao, Bing Gao and Jinbo Hu* 

J. Fluorine Chem. 2012, 143,  161-166. 文章链接

 

 

6. Difluoro(phenylchalcogen)methylation of aldehydes, ketones, and imines with S-, Se-, and Te-containing reagents PhXCF₂H (X = S, Se, Te). 

Mingyou Hu, Fei Wang, Zhengbiao He, Wei Zhang, and Jinbo Hu* 

J. Fluorine Chem. 2012, 135, 45-58. 文章链接 

 

 

7. Nucleophilic difluoromethylation of CN bonds in heterocycles with difluoromethyl silane reagents. 

Weizhou Huang, Chuanfa Ni, Yanchuan Zhao, Wei Zhang, Alexander D. Dilman, and Jinbo Hu* 

Tetrahedron. 2012, 68 , 5137-5144. 文章链接

 

 

1. Efficient and Direct Nucleophilic Difluoromethylation of Carbonyl Compounds and Imines with Me₃SiCF₂H at Ambient or Low Temperature. 

Yanchuan Zhao, Weizhou Huang, Ji Zheng, and Jinbo Hu* 

Org. Lett. 2011, 13 , 5342–5345. 文章链接

 

 

2. Nucleophilic Fluoromethylation of Aldehydes with Fluorobis(phenylsulfonyl) methane: The Importance of Strong Li–O Coordination and Fluorine Substitution for C–C Bond Formation. 

Xiao Shen, Laijun Zhang, Yanchuan Zhao, Guangyu Li, and Jinbo Hu* 

Angew. Chem. Int. Ed. 2011, 123 , 2636–2640. 文章链接

 

 

3. Copper-Mediated Fluoroalkylation Reactions with [(Phenylsulfonyl)-difluoro methyl] trimethylsilane: Synthesis of PhSO₂CF₂–Containing Allenes and Alkynes. 

Jieming Zhu, Fei Wang, Weizhou Huang, Yanchuan Zhao, Wenchao Ye, and Jinbo Hu* 

Synlett  2011, 7, 899–902. 文章链接

 

 

1. Difluoromethyl 2-Pyridyl Sulfone: A New gem-Difluoroolefination Reagent for Aldehydes and Ketones. 

Yanchuan Zhao, Weizhou Huang, Lingui Zhu, and Jinbo Hu* 

Org. Lett. 2010, 12 , 1444-1447. 文章链接

 

 

 

2. Magnesium Metal-Mediated Reductive Trifluoromethylation of Aldehydes with Phenyl Trifluoromethyl Sulfone. 

Yanchuan Zhao, Jieming Zhu, Chuanfa Ni, and Jinbo Hu* 

Synthesis 2010, 11,  1899-1904. 文章链接

 

 

 

3. 1-tert-Butyl-1H-tetrazol-5-yl fluoromethyl sulfone (TBTSO₂CH₂F): a versatile fluoromethylidene synthon and its use in the synthesis of monofluorinated alkenes via Julia–Kocienski olefination. 

Lingui Zhu, Chuanfa Ni, Yanchuan Zhao, and Jinbo Hu* 

Tetrahedron 2010, 66 , 5089-5100. 文章链接

 

 

4. Nucleophilic (phenylsulfonyl)difluoromethylation of alkyl halides using PhSO₂CF₂SiMe3: preparation of gem-difluoroalkenes and trifluoromethyl compounds. 

Lingui Zhu, Ya Li, Yanchuan Zhao, and Jinbo Hu* 

Tetrahedron Lett. 2010, 51 , 6150-6152. 文章链接