2. Side-Chain Length and Dispersity in ROMP Polymers with Pore-Generating Side Chains for Gas Separations.
Francesco M. Benedetti, You-Chi Mason Wu, Sharon Lin, Yuan He, Erica Flear, Kayla R. Storme, Chao Liu, Yanchuan Zhao, Timothy M. Swager, and Zachary P. Smith*
3. Polymers with Side Chain Porosity for Ultrapermeable and Plasticization Resistant Materials for Gas Separations.
Yuan He, Francesco M. Benedetti, Sharon Lin, Chao Liu, Yanchuan Zhao, Hong‐Zhou Ye, Troy Van Voorhis, M. Grazia De Angelis, Timothy M. Swager, Zachary P. Smith*
5. Synthesis of 2,2-diaryl-1,1-difluoroethenes via Pd-catalyzed dehydrosulfonylative cross-coupling of α-[difluoro(phenylsulfonyl)methyl]benzyl tosylates with arylboronic acids.
Rui Zhang, Chuanfa Ni, Yanchuan Zhao, and Jinbo Hu*
2. Radical (2-pyridylsulfonyl)difluoromethylation of terminal alkenes with iododifluoromethyl 2-pyridyl sulfone.
Wemjun Miao, Chuanfa Ni, Yanchuan Zhao and Jinbo Hu* J. Fluorine Chem.2014, 167, 231-236. 文章链接
3. gem‐Difluoroolefination of Diaryl Ketones and Enolizable Aldehydes with Difluoromethyl 2‐Pyridyl Sulfone: New Insights into the Julia–Kocienski Reaction.
1. Copper-Mediated Fluoroalkylation of Aryl Iodides Enables Facile Access to Diverse Fluorinated Compounds: The Important Role of the (2-Pyridyl)sulfonyl Group.
Yanchuan Zhao, Bing Gao, Chuanfa Ni, and Jinbo Hu*
2. From Olefination to Alkylation: In-Situ Halogenation of Julia–Kocienski Intermediates Leading to Formal Nucleophilic Iodo- and Bromodifluoromethylation of Carbonyl Compounds.
5. Nucleophilic difluoromethylation of N,N-acetals with TMSCF2SO2Ph reagent promoted by trifluoroacetic acid: A facile access to α-difluoromethylated tertiary amines.
2. Nucleophilic Fluoromethylation of Aldehydes with Fluorobis(phenylsulfonyl) methane: The Importance of Strong Li–O Coordination and Fluorine Substitution for C–C Bond Formation.
3. Copper-Mediated Fluoroalkylation Reactions with [(Phenylsulfonyl)-difluoro methyl] trimethylsilane: Synthesis of PhSO2CF2–Containing Allenes and Alkynes.
Jieming Zhu, Fei Wang, Weizhou Huang, Yanchuan Zhao, Wenchao Ye, and Jinbo Hu*
3. 1-tert-Butyl-1H-tetrazol-5-yl fluoromethyl sulfone (TBTSO2CH2F): a versatile fluoromethylidene synthon and its use in the synthesis of monofluorinated alkenes via Julia–Kocienski olefination.
Lingui Zhu, Chuanfa Ni, Yanchuan Zhao, and Jinbo Hu*
4. Nucleophilic (phenylsulfonyl)difluoromethylation of alkyl halides using PhSO2CF2SiMe3: preparation of gem-difluoroalkenes and trifluoromethyl compounds.